| 纤维素-[2,3-(4-取代苯基)-6-(3,5-二氯苯基)]氨基甲酸酯的合成及作为HPLC手性固定相的手性识别 |
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| 引用本文： | 屈海涛,李峻青,沈军,沈贤德,罔本佳男. 纤维素-[2,3-(4-取代苯基)-6-(3,5-二氯苯基)]氨基甲酸酯的合成及作为HPLC手性固定相的手性识别[J]. 分析化学, 2011, 39(4): 461-465. DOI: 10.3724/SP.J.1096.2011.00461 |
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| 作者姓名： | 屈海涛 李峻青 沈军 沈贤德 罔本佳男 |
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| 作者单位： | 哈尔滨工程大学材料科学与化学工程学院;Nagoya University;Furo-cho;Chikusa-ku;Nagoya 464-8603;Japan; |
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| 基金项目： | 中央高校基本科研业务费专项资金(No.HEUCFT1009)资助项目 |
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| 摘 要： | 合成了3种新的纤维素苯基氨基甲酸酯类衍生物:纤维素-[2,3-二苯基-6(3,5-二氯苯基)]氨基甲酸酯、纤维素-[2,3-二(4-甲基苯基)-6-(3,5-二氯苯基)]氨基甲酸酯及[2,3-二(4-氯苯基)-6-(3,5-二氯苯基)]氨基甲酸酯,并将其涂敷在氨丙基硅胶表面制备 HPLC 手性固定相.利用<'1>H N...
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| 关 键 词： | 手性固定相(CSPs) 纤维素 手性识别 苯基氨基甲酸酯 |
Synthesis of Cellulose Carbamate Derivatives Bearing Phenyl or 4-Methylpheny or 4-Chlorophenyl Groups at 2-and 3-Positions and 3,5-Dichlorophenyl Group at 6-Position and Their Chiral Recognition as Chiral Packing Materials for High Performance Liquid Chrom |
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| QU Hai-Tao,LI Jun-Qing,SHEN Jun,SHEN Xian-De,Yoshio Okamoto. Synthesis of Cellulose Carbamate Derivatives Bearing Phenyl or 4-Methylpheny or 4-Chlorophenyl Groups at 2-and 3-Positions and 3,5-Dichlorophenyl Group at 6-Position and Their Chiral Recognition as Chiral Packing Materials for High Performance Liquid Chrom[J]. Chinese Journal of Analytical Chemistry, 2011, 39(4): 461-465. DOI: 10.3724/SP.J.1096.2011.00461 |
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| Authors: | QU Hai-Tao LI Jun-Qing SHEN Jun SHEN Xian-De Yoshio Okamoto |
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| Affiliation: | QU Hai-Tao1,LI Jun-Qing1,SHEN Jun1,SHEN Xian-De1,Yoshio Okamoto1,2 1(College of Material Science and Chemical Engineering,Harbin Engineering University,Harbin 150001)2(Nagoya University,Furo-cho,Chikusa-ku,Nagoya 464-8603,Japan) |
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| Abstract: | Three new cellulose phenylcarbamate derivatives,[6-(3,5-dichlorophenyl)-2,3-bisphenyl]carbamate(CSP-1),[6-(3,5-dichlorophenyl)-2,3-bis(4-methylphenyl)]carbamate(CSP-2) and [6-(3,5-dichlorophenyl)-2,3-bis(4-chlorophenyl)]carbamate(CSP-3) were synthesized and used as the chiral stationary phase for high performance liquid chromatography after coating on aminopropyl silica gel.The structures of the obtained derivatives were characterized by 1H NMR and IR spectroscopy.Ten racemates were used to evaluate their c... |
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| Keywords: | Chiral stationary phases Cellulose Chiral recognition Phenylcarbamate |
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