Stability of silver(I) glycinato complexes in water-acetone and water-isopropanol solvents |
| |
| Authors: | V A Isaeva Zh F Gesse V V Naumov V A Sharnin |
| |
| Institution: | (1) Ivanovo State University of Chemical Technology, pr. Engel’sa 7, Ivanovo, 153460, Russia |
| |
| Abstract: | The stability constants of silver(I) glycinato complexes in water-acetone and water-isopropanol solvents of various compositions have been studied potentiometrically at 298 K. The contributions of the ΔG° of reagent resolvation into the Gibbs free energy change of the complexing reaction have been estimated with reference to the literature data. The change in the solvation state of the ligand is decisive for the strengthening of silver(I) glycinato complexes in the water-organic solvents studied. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
