Auration of ruthenocene: synthesis and molecular structure of mono- and diaurated derivatives |
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| Authors: | M N Nefedova I A Mamed'yarova V I Sokolov E I Smyslova L G Kuz'mina K I Grandberg |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Ruthenocene, like ferrocene, reacts with (Ph3PAu)3O+BF4
– to afford agem-diaurated derivative CpRuC5H4(AuPPh3)2
+BF4
–, which is converted into CpRuC5H4AuPPh3 when treated with PPh3. X-ray structural analysis revealed substantial Ru-Au interaction in the diaurated derivative.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1335–1337, July, 1994.This work was supported by the Russian Foundation for Basic Research (projects 03-93-5827 and 03-93-18559). |
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| Keywords: | ruthenocene gold-containing oxonium salt auration |
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