Copper(II) oxalate and oxamate complexes |
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| Authors: | Novosad Josef Messimeri Argyro C Papadimitriou Christos D Veltsistas Panos G Woollins J Derek |
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| Institution: | (1) Department of Inorganic Chemistry, Masaryk University, Kotla sk 2, 611 37 Brno, Czech Republic;(2) Department of Chemistry, University of Ioannina, Ioannina, Greece;(3) School of Chemistry, University of St. Andrews, St. Andrews, Fife, KY16 9ST, Scotland |
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| Abstract: | Reaction of CuII salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives Cu(phen)(ox)(H2O)] · H2O or Cu(phen)(oxm)(H2O)] · H2O complexes while direct treatment of CuII salts with oxalate or oxamate gives NH4]2Cu(ox)2] and Cu(oxm)2(H2O)2] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported. |
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