Oxidative decarboxylation of cyclohexanecarbaldehyde in the presence of cyclooctane catalyzed by a binculear manganese(IV) complex |
| |
| Authors: | J. R. Lindsay-Smith G. B. Shul'pin |
| |
| Affiliation: | (1) Department of Chemistry, The University of York, YO1 5DD Heslington, York, UK;(2) N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977 Moscow, Russian Federation |
| |
| Abstract: | On heating, a MnIV complex initiates oxidation of cyclohexanecarbaldehyde with atmospheric oxygen in MeCN resulting in the formation of cyclohexanecarboxylic acid and considerable amounts of oxidative decarboxylation products (cyclohexane, cyclohexanol, and cyclohexanone). Cyclooctanol and cyclooctanone are also formed in the presence of cyclooctane. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2385–2387, November, 1998. |
| |
| Keywords: | alkanes, cyclooctane, aldehydes, oxidation, oxygen, activation of C− H bond, decarboxylation, radicals manganese complexes, metallocomplex catalysis |
| 本文献已被 SpringerLink 等数据库收录！ |
|
