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Upper Bound to the Expectation Value of the Squared Hamiltonian
Authors:M.G. Marmorino
Affiliation:(1) Department of Chemistry, Indiana University South Bend, South Bend, IN 46634, USA
Abstract:An upper bound to the expectation value of the squared Hamiltonian langH2rang is derived which relies on replacing products of certain operators with products of the matrix representations of said operators to reduce the computational demands of langH2rang. An example is given which shows the strength of the bound and an application with the Temple lower bound is shown.
Keywords:Hamiltonian  lower bounds  moments
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