Addition of diphenylphosphinoyl azide to [60]fullerene |
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| Authors: | I. P. Romanova O. G. Sinyashin G. G. Yusupova V. I. Kovalenko Yu. Ya. Efremov Yu. V. Badeev I. I. Vandyukova I. A. Arakelyan |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan, Russian Federation |
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| Abstract: | The reaction of [60]fullerene with diphenylphosphinoyl azide in toluene or ino-dichlorobenzene in the presence of traces of water affords 2-[N-(diphenylphosphoryl)amino]-1-hydroxy[60]fullerene This reaction in THF gives a mixture of (N-diphenylphosphoryl)[60]fullerenol[1,2-b]aziridine and a product of partial hydrolysis of the bisadduct of phosphorylated azide and fullerene. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2168–2172, November, 1999. |
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| Keywords: | [60]fullerene, phosphorylated azide cycloaddition aminohydroxyfullene phosphorylated aziridinofullerene synthesis structure hydrolysis |
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