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Addition of diphenylphosphinoyl azide to [60]fullerene |
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| Authors: | I P Romanova O G Sinyashin G G Yusupova V I Kovalenko Yu Ya Efremov Yu V Badeev I I Vandyukova I A Arakelyan |
| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan, Russian Federation |
| Abstract: | The reaction of 60]fullerene with diphenylphosphinoyl azide in toluene or ino-dichlorobenzene in the presence of traces of water affords 2-N-(diphenylphosphoryl)amino]-1-hydroxy60]fullerene This reaction in THF gives a mixture of (N-diphenylphosphoryl)60]fullerenol1,2-b]aziridine and a product of partial hydrolysis of the bisadduct of phosphorylated azide and fullerene. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2168–2172, November, 1999. |
| Keywords: | [60]fullerene phosphorylated azide cycloaddition aminohydroxyfullene phosphorylated aziridinofullerene synthesis structure hydrolysis |
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