A new stereoselective synthesis of 2-subsdtituted 1,3-bis(trimethylsilyl)propene derivatives and their conversion to cyclopentane and cyclohexane derivatives |
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| Authors: | Masahito Ochiai Kenzo Sumi Eiichi Fujita Motoo Shiro |
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| Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto-Fu 611, Japan;Shionogi Research Laboratories, Shionogi & Co. Ltd., Fukushima-ku, Osaka-fu 553, Japan |
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| Abstract: | Ester on treatment with sodium salt of sulfone or sulfoxide afforded 2-substituted 1,3-bis(trimethylsily)propene in good yield, from which cyclopentane and cyclohexane derivatives bearing a trimethylsilyl group in the molecules were synthesized. |
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