Cyclopropane formation from 4,5-unsaturated thiophenylethers: Conversion of limonene into car-2-ene |
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Authors: | J.D. Fourneron L.M. Harwood M. Julia |
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Affiliation: | Laboratoire de Chimie, Ecole Normale Supérieure, 24, rue Lomond, 75231 Paris Cedex 05, France |
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Abstract: | Strong bases can abstract a proton α to double bond. A phenylthio group ψ to that double bond can be eliminated at the same time leading to a cyclopropane ring. The procedure is illustrated by a conversion of limonene into car-2-ene. |
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