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Cyclopropane formation from 4,5-unsaturated thiophenylethers: Conversion of limonene into car-2-ene
Authors:J.D. Fourneron  L.M. Harwood  M. Julia
Affiliation:Laboratoire de Chimie, Ecole Normale Supérieure, 24, rue Lomond, 75231 Paris Cedex 05, France
Abstract:Strong bases can abstract a proton α to double bond. A phenylthio group ψ to that double bond can be eliminated at the same time leading to a cyclopropane ring. The procedure is illustrated by a conversion of limonene into car-2-ene.
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