Thermodynamic properties of citric acid and the system citric acid-water |
| |
| Authors: | CG de Kruif JC van Miltenburg AJJ Sprenkels G Stevens W de Graaf HGM de Wit |
| |
| Institution: | Department of General Chemistry, Chemical Thermodynamics Group, State University of Utrecht, De Uithof, 3508 TB Utrecht The Netherlands |
| |
| Abstract: | The binary system citric acid-water has been investigated with static vapour pressure measurements, adiabatic calorimetry, solution calorimetry, solubility measurements and powder X-ray measurements. The data are correlated by thermodynamics and a large part of the phase diagram is given. Molar heat capacities of citric acid are given from 90 to 330 K and for citric acid monohydrate from 120 to 300 K. The enthalpy of compound formation ΔcomH (298.15 K)=(?11.8±1) kJ mole?1. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
