The stereochemistry of cyclisation of n--butyldihydrocinnamamide to a β-lactam |
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| Authors: | Jack E. Baldwin Anthony P. Davis Leslie D. Field |
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| Affiliation: | The Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QY UK. |
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| Abstract: | Using a stereospecifically labelled precursor, the peroxide catalysed cyclisation of N--butyldihydrocinnamamide to the corresponding β-lactam was shown to proceed with complete loss of stereochemistry at the benzylic carbon atom. |
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