Stereospecific total synthesis of (±) pentenomycins by flash vacuum thermolysis of substituted tricyclo[5.2.1.02,6]decenones |
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| Authors: | J.M.J. Verlaak A.J.H. Klunder B. Zwanenburg |
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| Affiliation: | Department of Organic Chemistry, University of Nijmegen, Toernooiveld, 6525 ED Nijmegen, The Netherlands |
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| Abstract: | The synthesis of 4-functionalized tricyclo[5.2.1.02,6]decenones , starting from furans, is described. These structures are shown to be suitable precursors for the synthesis of cyclopentenoids such as pentenomycin and analogs. |
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