Biomimetic one-pot synthesis of nucleotide phosphates |
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| Authors: | Iwao Tabushi Jun-ichi Imuta |
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| Affiliation: | Contribution from Department of Synthetic Chemistry, Kyoto University, Sakyo-ku, Kyoto 606, Japan |
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| Abstract: | A strongly hydrophobic rigid diammonium, 1, an efficient extracting and transporting phase transfer reagent with high specificity for the pyrophosphate grouping, was used to synthesize ADP, ATP or ADP-NH2 in a hydrophobic medium. Thus, practically pure ADP-NH2 was obtained in 65% yield within 2 min. |
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