Adducts of copper(II) acetate with amines in ethanolic solution |
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| Authors: | Ralf Giesse Yoshitaka Gushikem Pedro L.O. Volpe |
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| Affiliation: | Instituto de Quimica, Universidade Estadual de Campinas, CP 1170, 13100 Campinas S.P. Brazil |
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| Abstract: | Copper(II) acetate was calorimetrically titrated with pyridine, 2-, 3- and 4-methylpyridine in absolute ethanol. The enthalpy of reaction and the equilibrium constant were determined for the adduct formation in solution for each ligand. The amines react with copper(II) acetate without breaking the dimeric structure at least in the limit of the concentration ratio|ligand|/|(CH3CO2)4Cu2|<2. |
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