| Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone |
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| 引用本文： | Jun LIU Qing Hua BIAN Ming An WANG Hong Chao GUO Min WANG. Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone[J]. 中国化学快报, 2006, 17(5): 606-608 |
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| 作者姓名： | Jun LIU Qing Hua BIAN Ming An WANG Hong Chao GUO Min WANG |
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| 作者单位： | Jun LIU，Qing Hua BIAN，Ming An WANG，Hong Chao GUO*，Min WANG* Department of Applied Chemistry，China Agricultural University，Beijing 100094 |
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| 摘 要： | Optically active TADDOL (α, α, α′, α′-tetraaryl-1, 3-dioxolane-4, 5-dimethanol) and the related ligands have played a significant role in asymmetric reactions1. Although several hundreds of different TADDOLs and TADDOL analogues have already been de
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| 关 键 词： | 合成 开链反应 TADDOL相似物 环丙烷 α α α＇ α＇-四芳基-1 3-二恶茂烷-4 5-二甲醇 |
| 收稿时间： | 2005-11-23 |
Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone |
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| Jun LIU,Qing Hua BIAN,Ming An WANG,Hong Chao GUO,Min WANG. Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone[J]. Chinese Chemical Letters, 2006, 17(5): 606-608 |
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| Authors: | Jun LIU Qing Hua BIAN Ming An WANG Hong Chao GUO Min WANG |
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| Abstract: | Synthesis and ring-opening reaction of TADDOL analogue with cyclopropane as chiral backbone were described. A plausible ring-opening and carbonium ion rearrangement mechanism have been proposed. |
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| Keywords: | TADDOL analogue ring-opening cyclopropane ring synthesis. |
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