| [C_（16）min]Br改性累托石的制备与性能研究 |
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| 引用本文： | 刘燕,侯琳熙.[C_（16）min]Br改性累托石的制备与性能研究[J].宁波大学学报(理工版),2011,24(2):71-74. |
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| 作者姓名： | 刘燕 侯琳熙 |
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| 作者单位： | 宁波大学材料科学与化学工程学院,浙江宁波,315211 |
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| 基金项目： | 2009年浙江省新苗人才计划项目; 2009年宁波大学研究生科研创新基金项目 |
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| 摘 要： | 以热稳定性较高的离子液体1-十六烷基-3-甲基咪唑溴盐（C16min]Br）为改性剂,以水为溶剂对累托石（REC）进行有机处理,制得离子液体型累托石（C16min]Br-REC）.通过元素分析考察了反应配比、制浆浓度、反应温度、反应时间、pH值对REC阳离子交换量（CEC）的影响,并通过红外光谱、X-射线衍射、透射电镜、热失重分析对有机累托石的结构和性能进行了表征.结果表明：改性后累托石层间距由2.23nm扩大到3.14nm,C16min]Br-REC的热分解温度比十六烷基三甲基溴化铵改性累托石（CTAB-REC）提高了71℃.
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| 关 键 词： | 累托石 离子液体 有机改性 热稳定性 |
Preparation and Characterization of [C_(16)min]Br-treated Rectorite |
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| LIU Yan,HOU Lin-xi.Preparation and Characterization of [C_(16)min]Br-treated Rectorite[J].Journal of Ningbo University(Natural Science and Engineering Edition),2011,24(2):71-74. |
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| Authors: | LIU Yan HOU Lin-xi |
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| Institution: | LIU Yan,HOU Lin-xi(Faculty of Materials Science and Chemical Engineering,Ningbo University,Ningbo 315211,China) |
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| Abstract: | In the process presented in this paper,Ionic liquid-treated rectorite is prepared with 1-hexadecyl-3-methylimidazolium bromide(C16min]Br) in water,and the resultant effects were investigated using elemental analysis into the cation exchange capacity(CEC) of mass ratio of the reactants,the slurry concentration,reaction time and temperature,and the pH value.In this paper,the structure and property of the modified rectorite are characterized with FTIR,XRD,TEM and TG.The optimal processing conditions for the o... |
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| Keywords: | rectorite ionic liquid organic modification thermal properties |
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