| MP-C60(M=Cu,Co)化合物的合成、表征及光电性能研究 |
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| 基金项目： | 福建省自然科学基金;厦门大学校科研和教改项目 |
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| 摘 要： |
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| 关 键 词： | 卟啉 富勒烯 光电性能 |
Synthesis, Characterization and Photovoltaic Effect of Porphyrin-Fullerene Compounds MP-C60 |
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| Yang Sengen,Fan Suhua,Liu Jianyong,Wu Zhenyi,Tian Ling,Lin Yongsheng,Zhan Mengxiong. Synthesis, Characterization and Photovoltaic Effect of Porphyrin-Fullerene Compounds MP-C60[J]. Chinese Journal of Chemical Physics, 2005, 18(5): 654-656. DOI: 10.1088/1674-0068/18/5/654-656 |
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| Authors: | Yang Sengen Fan Suhua Liu Jianyong Wu Zhenyi Tian Ling Lin Yongsheng Zhan Mengxiong |
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| Abstract: | The convalently linked porphyrin-fullerene ligand was synthesized by 1,3 dipolar cycloaddition reaction. The ligand and complexes were characterized by means of FT-IR, Uv-Vis, 1HNMR, ESI-MS and elemental analysis. The photoelectricity transform performance of the compounds was studied.The result indicated that the photovoltaic effect of (n+n) heterojunction electrode formed by MP-C60/GaAs was super, especially in the I2/I3- and O2／H2O redox couples, and photovoltaic potential was preferable. The photovoltaic performance of a MP-C60/GaAs electrode at 1-2 μm thinck MP-C60 film of appeared peak value. |
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| Keywords: | Porphyrin Fullerene Photovoltaic effect |
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