Original ring contraction of triazine derivatives to 1,2,4-thiadiazoles |
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| Authors: | Vincent Kikelj Karine Julienne Jean-Claude Meslin David Deniaud |
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| Affiliation: | aCNRS, UMR 6230, Université de Nantes, Chimie et Interdisciplinarité: Synthèse Analyse Modélisation, UFR Sciences et Techniques, 2 Rue de la Houssinière, BP92208, 44322 Nantes Cedex 03, France |
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| Abstract: | The oxidation of triazines 1 is described here. While treatment with m-CPBA or DMDO led to formation of a mixture of compounds, [TBA-OX] oxidation led exclusively to thiadiazoles 2 by ring contraction reaction. |
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| Keywords: | Ring contraction Oxone Thiadiazole Oxidation Triazine |
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