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Alkyl Esters of 2-[5-Chloro(bromo)-6-methoxy-4-methylpyrimidinyl-2-oxy]alkanoic Acids |
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| Authors: | V V Dovlatyan K A Eliazyan V A Pivazyan E A Kazaryan A P Engoyan |
| Institution: | (1) Armenian Agricultural Academy, Yerevan, 375009, Armenia |
| Abstract: | The reaction of a mixture of formaldehyde and sodium cyanide or of lactic acid nitrile with trimethyl(6-methoxy-4-methylpyrimidinyl-2)ammonium chloride give the 2-(6-methoxy-4-methylpyrimidinyl-2-oxy)alkanoic acid nitriles. They were subsequently converted to the corresponding alkyl esters by a Pinner reaction and then to their 2-(5-halo-6-methoxy-4-methylpyrimidinyl-2-oxy) derivatives using N-halosuccinimides. |
| Keywords: | halosuccinimides pyrimidinyloxyalkanoic acid nitriles and esters cyanomethylating mixture |
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