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AMORPHOUS POLY(ETHYLENE TEREPHTHALATE) FILMS IN THE STATE OF HIGH GLOBAL CHAIN ORIENTATION BUT NEARLY RANDOM SEGMENTAL ORIENTATION
作者姓名:钱人元  范庆荣  关家玉  蔡忠龙  Shigeyoshi Osaki
作者单位:Institute of Chemistry,the Chinese Academp of Sciences,Beijing 100080,China,Institute of Chemistry,the Chinese Academp of Sciences,Beijing 100080,China,Institute of Chemistry,the Chinese Academp of Sciences,Beijing 100080,China,Faculty of Applied Sciences and Textiles,the Hong Kong Polytechnic University,Hung Hom,Kowloon,Hong Kong,Mycal Institute,Inc.,2-2-9 Awajimachi,Chuo-ku,Osaka,541 Japan
摘    要:The isotropy or anisotropy in some physical properties of the ammorphous poly(ethyleneterephthalate) films uniaxially drawn at temperatures above its T_g and then quenched toroom temperature have been studied. Experimental results here presented show that thisamorphous state of high global chain orientation but nearly random segmental orientation,the GOLR state, is nearly isotropic in refractive indices and Young's modulus for smalldeformation, while it is very probably anisotropic in thermal conduction and microwavedielectric properties.

收稿时间:1997-03-25

AMORPHOUS POLY(ETHYLENE TEREPHTHALATE) FILMS IN THE STATE OF HIGH GLOBAL CHAIN ORIENTATION BUT NEARLY RANDOM SEGMENTAL ORIENTATION
QIAN Renyuan,FAN Qingrong,GUAN Jiayu,Chung Long Choy,Shigeyoshi Osaki.AMORPHOUS POLY(ETHYLENE TEREPHTHALATE) FILMS IN THE STATE OF HIGH GLOBAL CHAIN ORIENTATION BUT NEARLY RANDOM SEGMENTAL ORIENTATION[J].Chinese Journal of Polymer Science,1997,0(3):199-204.
Authors:QIAN Renyuan  FAN Qingrong  GUAN Jiayu  Chung Long Choy  Shigeyoshi Osaki
Institution:Institute of Chemistry; the Chinese Academp of Sciences; Beijing; China; Faculty of Applied Sciences and Textiles; the Hong Kong Polytechnic University; Hung Hom; Kowloon; Hong Kong; Mycal Institute; Inc.; 2-2-9 Awajimachi; Chuo-ku; Osaka; 541 Japan
Abstract:The isotropy or anisotropy in some physical properties of the ammorphous poly(ethyleneterephthalate) films uniaxially drawn at temperatures above its T_g and then quenched toroom temperature have been studied. Experimental results here presented show that thisamorphous state of high global chain orientation but nearly random segmental orientation,the GOLR state, is nearly isotropic in refractive indices and Young's modulus for smalldeformation, while it is very probably anisotropic in thermal conduction and microwavedielectric properties.
Keywords:Orientation  Uniaxial stretching  Refractive indices  Ultrasonic moduli  Thermal conductivities  Microwave dielectric properties
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