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稻壳生物油的燃烧及污染物排放特性研究
引用本文:刘承运,陆强,孙书生,张栋,朱锡锋. 稻壳生物油的燃烧及污染物排放特性研究[J]. 燃料化学学报, 2008, 36(5): 577-582
作者姓名:刘承运  陆强  孙书生  张栋  朱锡锋
作者单位:LIU Cheng-yun, LU Qiang, SUN Shu-sheng, ZHANG Dong, ZHU Xi-feng
基金项目:国家自然科学基金,国家重点基础研究发展计划(973计划),中国科学院方向性项目
摘    要:对稻壳生物油在空气气氛下进行了热重分析,并计算得到生物油的挥发、降解和残炭燃烧的活化能分别为63.11kJ/mol、81.01kJ/mol和161.29kJ/mol。在自砌的小型工业窑炉上开展了生物油燃烧实验,研究了生物油的点火工艺和燃烧污染物的排放规律。通过调整喷雾速度和喷嘴结构,在炉膛预热并使用明火点火源的情况下,生物油可以顺利点火。生物油燃烧容易生成CO,提高过量空气系数能有效地控制CO的生成,但同时会生成更多的NOx。在生物油中添加甲醇和乙醇助剂后,点火容易,燃烧温度提高,尾气中CO和NOx含量都一定程度的下降。

关 键 词:生物油; 热重分析; 燃烧; 窑炉; 污染物  
收稿时间:2008-02-01
修稿时间:2008-05-26

Research on rice husk bio-oil combustion and pollutant emissions
LIU Cheng-yun,LU Qiang,SUN Shu-sheng,ZHANG Dong,ZHU Xi-feng. Research on rice husk bio-oil combustion and pollutant emissions[J]. Journal of Fuel Chemistry and Technology, 2008, 36(5): 577-582
Authors:LIU Cheng-yun  LU Qiang  SUN Shu-sheng  ZHANG Dong  ZHU Xi-feng
Abstract:The thermogravimetric analysis of the rice husk bio-oil under the air atmosphere was performed. The activation energies for the volatilization, decomposition and char combustion of bio-oil are obtained to be 63.11kJ/mol, 81.01kJ/mol and 161.29kJ/mol, respectively. The experiments for the bio-oil combustion were carried out in a small kiln to focus on the ignition and pollutant emission characteristics. With the modification of the nozzle and the adjustment of the spray velocity, the bio-oil can be ignited successfully by using a pilot flame to preheat the kiln chamber. Bio-oil combustion has the tendency to form CO, which can be effectively reduced with a higher excess air ratio, but the formation of NOx will be increased. By adding methanol or ethanol into bio-oil, the ignition of bio-oil becomes easy, the temperature of combustion is increased, and the formation of CO and NOx is decreased.
Keywords:bio-oil  thermogravimetric analysis  combustion  kiln  pollutant emission  
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