ESR studies of T3+ complexes formed in the catalytic system TiCl2(acac)1+Et2AlCl and their interaction with ethylene, carbon monoxide and pyridine |
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Authors: | V A Poluboyarov P M Nedorezova V F Anufrienko F S Diachkovskii V I Tsvetkova and V A Zakharov |
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Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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Abstract: | Coordination state of Ti3+ions formed in the homogeneous catalytic systems TiCl2(acac)2+Et2AlCl, and its changes upon interaction with ethylene, carbon monoxide and pyridine have been studied by ESR.
![Mcy](/content/w67286216365q2lt/xxlarge1052.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![dcy](/content/w67286216365q2lt/xxlarge1076.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![Ecy](/content/w67286216365q2lt/xxlarge1069.gif) ![Pcy](/content/w67286216365q2lt/xxlarge1055.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![zcy](/content/w67286216365q2lt/xxlarge1079.gif) ![ucy](/content/w67286216365q2lt/xxlarge1091.gif) ![chcy](/content/w67286216365q2lt/xxlarge1095.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![kcy](/content/w67286216365q2lt/xxlarge1082.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![rcy](/content/w67286216365q2lt/xxlarge1088.gif) ![dcy](/content/w67286216365q2lt/xxlarge1076.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![tscy](/content/w67286216365q2lt/xxlarge1094.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![yacy](/content/w67286216365q2lt/xxlarge1103.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) Ti3+, ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![bcy](/content/w67286216365q2lt/xxlarge1073.gif) ![rcy](/content/w67286216365q2lt/xxlarge1088.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![zcy](/content/w67286216365q2lt/xxlarge1079.gif) ![ucy](/content/w67286216365q2lt/xxlarge1091.gif) ![yucy](/content/w67286216365q2lt/xxlarge1102.gif) ![shchcy](/content/w67286216365q2lt/xxlarge1097.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![khcy](/content/w67286216365q2lt/xxlarge1093.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![gcy](/content/w67286216365q2lt/xxlarge1075.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![mcy](/content/w67286216365q2lt/xxlarge1084.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![gcy](/content/w67286216365q2lt/xxlarge1075.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![kcy](/content/w67286216365q2lt/xxlarge1082.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![lcy](/content/w67286216365q2lt/xxlarge1083.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![chcy](/content/w67286216365q2lt/xxlarge1095.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![kcy](/content/w67286216365q2lt/xxlarge1082.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![mcy](/content/w67286216365q2lt/xxlarge1084.gif) TiCl2(acac)2=Et2AlCl, ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![kcy](/content/w67286216365q2lt/xxlarge1082.gif) ![zhcy](/content/w67286216365q2lt/xxlarge1078.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![gcy](/content/w67286216365q2lt/xxlarge1075.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![zcy](/content/w67286216365q2lt/xxlarge1079.gif) ![mcy](/content/w67286216365q2lt/xxlarge1084.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![pcy](/content/w67286216365q2lt/xxlarge1087.gif) ![rcy](/content/w67286216365q2lt/xxlarge1088.gif) ![vcy](/content/w67286216365q2lt/xxlarge1074.gif) ![zcy](/content/w67286216365q2lt/xxlarge1079.gif) ![acy](/content/w67286216365q2lt/xxlarge1072.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![mcy](/content/w67286216365q2lt/xxlarge1084.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![dcy](/content/w67286216365q2lt/xxlarge1076.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![jcy](/content/w67286216365q2lt/xxlarge1081.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![vcy](/content/w67286216365q2lt/xxlarge1074.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![ecy](/content/w67286216365q2lt/xxlarge1101.gif) ![tcy](/content/w67286216365q2lt/xxlarge1090.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![lcy](/content/w67286216365q2lt/xxlarge1083.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) , ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![kcy](/content/w67286216365q2lt/xxlarge1082.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![scy](/content/w67286216365q2lt/xxlarge1089.gif) ![softcy](/content/w67286216365q2lt/xxlarge1100.gif) ![ucy](/content/w67286216365q2lt/xxlarge1091.gif) ![gcy](/content/w67286216365q2lt/xxlarge1075.gif) ![lcy](/content/w67286216365q2lt/xxlarge1083.gif) ![iecy](/content/w67286216365q2lt/xxlarge1077.gif) ![rcy](/content/w67286216365q2lt/xxlarge1088.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) ![dcy](/content/w67286216365q2lt/xxlarge1076.gif) ![pcy](/content/w67286216365q2lt/xxlarge1087.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![rcy](/content/w67286216365q2lt/xxlarge1088.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![dcy](/content/w67286216365q2lt/xxlarge1076.gif) ![icy](/content/w67286216365q2lt/xxlarge1080.gif) ![ncy](/content/w67286216365q2lt/xxlarge1085.gif) ![ocy](/content/w67286216365q2lt/xxlarge1086.gif) .
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