Bidirectional transfer of phenyl and methyl groups between Pt(IV) and boron in platinum dipyridylborato complexes |
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| Authors: | Khaskin Eugene Zavalij Peter Y Vedernikov Andrei N |
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| Institution: | Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA. |
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| Abstract: | In the presence of weakly Lewis basic DMSO methyl group migration between B and PtIV in dipyridylborato trihydrocarbyl PtIV complexes is reversible; the preferred direction of Ph group migration in THF solution is from PtIV to B. |
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