Aziridination of aliphatic alkenes catalyzed by N-heterocyclic carbene copper complexes |
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Authors: | Xu Qun Appella Daniel H |
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Institution: | Laboratory of Bioorganic Chemistry, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, DHHS, 9000 Rockville Pike, Bethesda, Maryland 20892, USA. |
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Abstract: | A copper-catalyzed aziridination of aliphatic alkenes promoted by N-heterocyclic carbene ligands is described. The readily available catalyst IPrCu(DBM) can catalyze aziridination of a variety of aliphatic alkenes using alkenes as the limiting reagents. |
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