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Aziridination of aliphatic alkenes catalyzed by N-heterocyclic carbene copper complexes
Authors:Xu Qun  Appella Daniel H
Institution:Laboratory of Bioorganic Chemistry, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, DHHS, 9000 Rockville Pike, Bethesda, Maryland 20892, USA.
Abstract:A copper-catalyzed aziridination of aliphatic alkenes promoted by N-heterocyclic carbene ligands is described. The readily available catalyst IPrCu(DBM) can catalyze aziridination of a variety of aliphatic alkenes using alkenes as the limiting reagents.
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