Synthesis and Structural Chemistry of Tungstoarsenates(V) |
| |
| Authors: | Roland Contant René Thouvenot Yves Dromzée Anna Proust Pierre Gouzerh |
| |
| Institution: | (1) Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR CNRS 7071, FR 1269, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France |
| |
| Abstract: | An overview of the synthesis and of the structural chemistry of tungstoarsenates(V) of the 1:12 and 2:21 families is presented with special emphasis on the 2:20 species. The molecular structure of As2W20O71(H2O)3]12− has been determined by single-crystal X-ray diffraction of K12As2W20O71(H2O)3]·23H2O and that of As2W20O70(H2O)2]10− has been inferred from a 183W NMR study in aqueous solution.This paper is dedicated to Professor Michael Pope in recognition of his invaluable contribution to polyoxometalate chemistry. |
| |
| Keywords: | Tungstoarsenates(V) synthesis crystal structure 183W NMR |
| 本文献已被 SpringerLink 等数据库收录！ |
