关于超Raman效应中散射强度的计算

本文根据辐射的量子理论,对超Raman散射强度进行了计算。从理论上直接断言:所有具有振动红外活性的Raman介质都同时具有振动超Raman活性。由于偶极跃迁几率只对反Stokes超Raman散射线有贡献,所以反Stokes线与Stokes线的强度公式不对称,前者含有更丰富的频谱。并且对于低波数频移,即使在室温条件下,两者也几乎有同数量级的强度。最后讨论了超Raman散射中的共振效应。关键词：

CALCULATION ON SCATTERING INTENSITIES OF HYPER-RAMAN EFFECT

In this paper, hyper-Raman scattering intensities are calculated based on the quantum theory of radiation. From the intensity formulae, we can conclude directly that all Raman material that has vibration infra-red activity must have vibration hyper-Raman activity simultaneously. Because probability of dipole transition only contributes to anti-Stokes hyper-Raman scattering intensity, the intensity formulae of the anti-Stokes and Stokes are asymmetric, and the former consists of richer spectra than the latter. For the frequency shift of low wave number, the two intensities are almost identical even at room temperature. Finally, the resonance hyper-Raman scattering is also discussed.