Synthesis and characterization of [Co(NH3)5NO2][M(NO2)4] (M = Pt, Pd) compounds and their thermolysis products |
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| Authors: | K V Yusenko Yu V Shubin O N Skryabina I A Baidina S V Korenev |
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| Institution: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia;(2) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia |
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| Abstract: | Compounds Co(NH3)5NO2]Pd(NO2)4] (I) and Co(NH3)5NO2]Pt(NO2)4] · 1.5H2O (II) have been crystallized from solution. Their crystal structures have been solved, and thermolysis under various conditions studied. The thermolysis products are Co0.5M0.5 ordered solid solutions. |
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