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Some solvable models of nonuniform classical fluids
Authors:J. K. Percus
Affiliation:(1) Courant Institute of Mathematical Sciences and Physics Department, New York University, 10012 New York, New York
Abstract:A model classical fluid is constructed by assuming that the direct correlation functionc(r – rprime) is independent of any applied external field. Thermodynamic consistency requires thatc(r – rprime) ges 0, and permits explicit representation of the model by a many-body interaction potential. In the canonical ensemble, the model shows a phase transition to an infinite density condensed phase, but in the grand canonical ensemble only an anomalous transition to zero density vapor is found to stably exist.
Keywords:Nonuniform fluid  density functional  many-body forces  phase transition
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