Separated local field spectroscopy of columnar and nematic liquid crystals |
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Authors: | Dvinskikh Sergey V Zimmermann Herbert Maliniak Arnold Sandström Dick |
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Affiliation: | Division of Physical Chemistry, Arrhenius Laboratory, Stockholm University, SE-10691 Stockholm, Sweden. sergey@physc.su.se |
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Abstract: | We are in this work comparing the efficiencies of various 1H-13C separated local field (SLF) experiments when applied to columnar and nematic liquid crystals. In particular, the performances of the conventional SLF, proton-detected local field (PDLF), and polarization inversion spin exchange at the magic angle (PISEMA) methods in terms of spectral resolution, robustness, and ability to measure long-range couplings are investigated. The PDLF sequence provides in most cases the best dipolar resolution. This is especially obvious for weakly coupled 1H-13C spin pairs. |
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