| 新型多齿手性氨基醇的合成和结构表征 |
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| 引用本文： | 刘丰良,刘言萍,沈霞,尹军,肖清波,孙凯. 新型多齿手性氨基醇的合成和结构表征[J]. 化学研究, 2012, 23(4): 6-8 |
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| 作者姓名： | 刘丰良 刘言萍 沈霞 尹军 肖清波 孙凯 |
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| 作者单位： | 中南大学 化学化工学院,湖南长沙,410083 |
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| 基金项目： | 国家大学生创新训练项目，中南大学研究生学位论文创新项目 |
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| 摘 要： | 以L-苯甘氨酸和N,N-二甲基苯胺为原料,合成了2种新型多齿手性氨基醇S-1,1,2-三苯基-2-[(2-二甲氨基-5-溴-1-苯基)甲氨基]-1-乙醇和S-2-苯基-2-[(2-二甲氨基-5-溴-1-苯基)甲氨基]-1-乙醇;利用红外光谱仪、核磁共振谱仪及质谱仪表征了合成产物的结构.
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| 关 键 词： | L-苯甘氨酸 N,N-二甲基苯胺 多齿手性氨基醇 合成 结构表征 |
Synthesis and structure characterization of novel polydentate chiral amino alcohols |
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| LIU Feng-liang , LIU Yan-ping , SHEN Xia , YIN Jun , XIAO Qing-bo , SUN Kai. Synthesis and structure characterization of novel polydentate chiral amino alcohols[J]. Chemical Research, 2012, 23(4): 6-8 |
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| Authors: | LIU Feng-liang LIU Yan-ping SHEN Xia YIN Jun XIAO Qing-bo SUN Kai |
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| Affiliation: | (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, China) |
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| Abstract: | Two novel polydentate chiral amino alcohols,S-2-[（5-bromo-2-dimethylamino-1-phenyl）methylamino]-1,1,2-triphenyl-1-ethanol and S-2-[（5-bromo-2-dimethylamino-1-phenyl）methylamino]-2-phenyl-1-ethanol,were conveniently and effectively synthesized from L-benzene glycine and N,N-dimethylaniline as the starting materials.The structure of as-synthesized products was characterized by means of infrared spectrometry,nuclear magnetic resonance spectroscopy,and mass spectrometry. |
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| Keywords: | L- benzene glycine N, N-dimethylaniline polydentate chiral amino alcohol synthe-sis structure characterization |
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