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Reduction of NO by Propene Over Pt, Pd and Rh-Based ZSM-5 Under Lean-Burn Conditions
Authors:Javier Pérez-Ramírez  Jorge M García-Cortés  María José Illán-Gómez  Freek Kapteijn  Jacob A Moulijn and Concepción Salinas-Martínez de Lecea
Institution:(1) Industrial Catalysis, DelftChemTech, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands;(2) Department of Inorganic Chemistry, University of Alicante, P.O. Box 99, E-03080 Alicante, Spain
Abstract:Selective catalytic reduction of NO by propene has been investigated over noble metal (Pt, Pd, Rh)-based ZSM-5 catalysts. These samples were tested in a gas mixture system in the presence of excess oxygen, simulating lean-burn exhaust gases. The sequence in activity for NO reduction was Pt > Rh sim Pd. Regarding the selectivity of the reaction to N2, an opposite trend was observed: Rh > Pd sim Pt. The catalytic systems have presented stable operation under isothermal conditions during time-on-stream experiments.
Keywords:de-NOx  HC-SCR  noble metal  ZSM-5
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