Resin-immobilized CuO and Cu nanocomposites for alcohol oxidation |
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| Authors: | Pande Surojit Saha Arindam Jana Subhra Sarkar Sougata Basu Mrinmoyee Pradhan Mukul Sinha Arun Kumar Saha Sandip Pal Anjali Pal Tarasankar |
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| Affiliation: | Department of Chemistry and Civil Engineering, Indian Institute of Technology, Kharagpur, India. |
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| Abstract: | Resin immobilized stable, spherical CuO nanoparticles prepared in the presence of cyclodextrin (CD) act as catalysts for liquid phase alcohol oxidation in air. The catalytic activity of the CuO nanocomposites and its green chemistry approach make it superior to the related resin-bound Cu(0) nanocomposite. The effect of alcohol chain length and electron-donating or -withdrawing groups influence product yield. The nanocomposites exhibit good reusability, simple workup procedure, and a straightforward approach to aldehyde formation. |
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