Homolytic addition of dithiols to alkynes: A new approach to the construction of dithiacyclanes and crown thioethers |
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| Authors: | E I Troyansky D V Demchuk G I Nikishin |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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| Abstract: | A novel general approach to the construction of sulfur-containing heterocyclic compounds and crown thioethers based on one-pot
“assembling” of their molecules from α,ω-dithiols and alkynesvia homolytic cycloaddition has been developed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1256–1267, July, 1997. |
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| Keywords: | homolytic cycloaddition homolytic macrocyclization α ω -dithiols alkynes dithiacyclanes crown thioethers |
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