A thallium mediated route to sigma-arylalkynyl complexes of bipyridyltricarbonylrhenium(I) |
| |
| Authors: | Liddle Brendan J Lindeman Sergey V Reger Daniel L Gardinier James R |
| |
| Affiliation: | Department of Chemistry, Marquette University, Milwaukee, Wisconsin 53211, USA. |
| |
| Abstract: | A simple, one-pot preparation of rhenium(I) sigma-arylalkynyl complexes is reported using thallium(I) hexafluorophosphate as a halogen abstraction agent. This new route to rhenium sigma-alkynyls enjoys higher yields compared to analogous preparations using silver salts by eliminating potential electrochemical degradation pathways. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
