Oxomolybdenum(VI) and (V) complexes with 6–methyl-4–hydroxypyrimidinyl hydrazones |
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Authors: | Chabanur Hanamant S. Revankar Vidyanand K. Mahale Vinayak B. |
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Affiliation: | (1) Department of Chemistry, Karnatak University, Dharwad, 580 003, India |
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Abstract: | Dioxomolybdenum(VI) complexes [MoO2(L)H2O] and oxomolybdenum(V) complexes [Mo2O3(LH)2Cl2] (where LH2=hydrazones derived from 6–methyl-4–hydroxy-2–hydrazinopyrimidine with salicylaldehyde, 5–methyl-, 5–chloro-, 5–bromo-, 3–methoxy-salilcylaldehyde, or 2–hydroxy-1–naphthaldehyde) have been prepared and characterised by spectroscopic and physico-chemical methods. The MoVI complexes are diamagnetic octahedral structures, whilst the MoV complexes are paramagnetic and probably dimeric, via oxobridging. |
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