Oxomolybdenum(VI) and (V) complexes with 6–methyl-4–hydroxypyrimidinyl hydrazones

Dioxomolybdenum(VI) complexes MoO2(L)H2O] and oxomolybdenum(V) complexes Mo2O3(LH)2Cl2] (where LH2=hydrazones derived from 6–methyl-4–hydroxy-2–hydrazinopyrimidine with salicylaldehyde, 5–methyl-, 5–chloro-, 5–bromo-, 3–methoxy-salilcylaldehyde, or 2–hydroxy-1–naphthaldehyde) have been prepared and characterised by spectroscopic and physico-chemical methods. The MoVI complexes are diamagnetic octahedral structures, whilst the MoV complexes are paramagnetic and probably dimeric, via oxobridging.