Addition of bromine to 2-methyl-2-azabicyclo[2.2.1]hept-5-ene |
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| Authors: | M N Bulanov S E Sosonyuk N V Zyk |
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| Institution: | (1) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899 Moscow, Russian Federation |
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| Abstract: | Addition of bromine to 2-methyl-2-azabicyclo2.2.1]hept-5-ene was studied. Unexpectedly, 3-bromo-1-methyl-1-azoniatricyclo2.2.1.02,6]heptane tribromide was isolated rather than the product of bromine addition to the double bond. The former reacted with the starting alkene in a polar solvent to form the corresponding monobromide. |
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| Keywords: | azabicycloheptenes bromination azoniatricycloheptanes aziridines quaternary ammonium bases |
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