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木薯淀粉硫酸酯的制备及理化性质
引用本文:刘绍秀,张友全,覃雯,玉琼广,刘洁.木薯淀粉硫酸酯的制备及理化性质[J].化学研究,2011,22(4):56-59.
作者姓名:刘绍秀  张友全  覃雯  玉琼广  刘洁
作者单位:1. 广西大学化学化工学院,广西南宁,530004
2. 广西明阳生化科技股份有限公司,广西南宁,530226
基金项目:广西科技攻关项目(桂科合-10100022-7); 南宁市科技攻关项目(南科发(2010)03015A)
摘    要:以NaHSO3和NaNO2为酯化剂,采用水相法制备了低取代度的淀粉硫酸酯(SSE),测定了SSE糊的冻融稳定性、凝沉性能、透明度、黏度;利用红外光谱仪分析了产物的化学结构.结果表明,酯化的SSE糊的透光率比淀粉的提高22.4%,透明度稳定性明显增强;SSE糊的黏度冷热差值均比淀粉的低,抗老化性能增强、凝沉性能得以改善,...

关 键 词:木薯淀粉硫酸酯  低取代度  制备  理化性质

Preparation and physicochemical property of cassava starch sulfate esters
LIU Shao-xiu,ZHANG You-quan,QIN Wen,YU Qiong-guang,LIU Jie.Preparation and physicochemical property of cassava starch sulfate esters[J].Chemical Research,2011,22(4):56-59.
Authors:LIU Shao-xiu  ZHANG You-quan  QIN Wen  YU Qiong-guang  LIU Jie
Institution:LIU Shao-xiu1,ZHANG You-quan1,QIN Wen1,YU Qiong-guang2,LIU Jie2(1.School of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,Guangxi,China,2.Guangxi Mingyang Biochemical Technology Company Ltd.,Nanning 530226,China)
Abstract:Starch sulfate ester(SSE) with a low degree of substitution was synthesized from cassava starch in aqueous solution in the presence of NaHSO3 and NaNO2 as the esterification agents.The freeze-thaw stability,anti-aging capacity,transparency and viscosity of as-synthesized SSE paste were determined,and its chemical structure was analyzed by means of infrared spectrometry(IR).Results show that after esterification,the transparency of the SSE paste was increased by 22.4%,and its transparency stability was enhan...
Keywords:cassava starch sulfate ester  low degree of substitution  preparation  physicochemical property  
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