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多孔炭物理化学结构及其表征
引用本文:吴明铂,郑经堂,邱介山. 多孔炭物理化学结构及其表征[J]. 化学通报, 2011, 0(7): 617-627
作者姓名:吴明铂  郑经堂  邱介山
作者单位:中国石油大学(华东)重质油国家重点实验室;大连理工大学化工学院材料化工系炭素材料研究室;
基金项目:教育部新世纪优秀人才支持计划(NCET-10-0768),教育部科学技术重点项目(109100); 国家自然科学基金项目(20876176,20836002,20725619,20976196); 中央高校基本科研业务费专项资金(09CX04037A); 山东省博士基金项目(2008BS09013)资助
摘    要:以碳为基本骨架的多孔炭因具有丰富的孔隙结构和表面化学宫能团,在吸附分离、催化、电子等领域应用广泛.在阐述多孔炭孔结构(物理结构)和表面化学宫能团(化学结构)基础上,重点介绍了透射电镜等可直接观察多孔炭孔结构的表征方法及Dubinin微孔充填理论、平均场密度泛函理论、吸附法、压汞法等表征多孔炭孔结构的主要理论及方法,以及...

关 键 词:多孔炭  孔结构  表面化学结构  表征

Physical and Chemical Structures of Porous Carbon and Their Characterizations
Wu Mingbo,Zheng Jingtang,Qiu Jieshan. Physical and Chemical Structures of Porous Carbon and Their Characterizations[J]. Chemistry, 2011, 0(7): 617-627
Authors:Wu Mingbo  Zheng Jingtang  Qiu Jieshan
Affiliation:Wu Mingbo1,Zheng Jingtang1,Qiu Jieshan2*(1State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Dongying 257061,2Carbon Research Laboratory,School of Chemical Engineering,Dalian University of Technology,Dalian 116012)
Abstract:Porous carbons with well-developed multi-scale pore structures and diversifying chemical functional groups have been widely used in many industrial fields including adsorption,separation,catalyst,etc.In this paper,the pore structure and surface chemical structure of porous carbon are discussed.Techniques including SEM and TEM to observe directly pore structures of porous carbon are introduced.Main theories and methods including micropore filling theory,mean-field density functional theory,and adsorption of ...
Keywords:Porous carbon  Pore structure  Surface chemical structure  Characterizations  
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