Kinetics of the reactions of p-nitrophenylbis(chloromethyl)phosphinate with primary and secondary amines |
| |
| Authors: | V E Bel'skii L S Novikova L A Kudryavtseva B E Ivanov |
| |
| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR |
| |
| Abstract: | Conclusions Study has been made of the kinetics of the reaction of p-nitrophenylbis(chloromethyl)-phosphinate with primary and secondary amines. Reaction proceeds through rupture of the ester bond at the P atom and is catalyzed by a second amine molecule. The reaction rate is determined by induction and steric effects in the amine substituents. The activation energy for the reaction with n-butylamine is negative.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1292–1295, June, 1977. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
