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Synthesis,characterization, catalytic and antimicrobial studies of ruthenium(III) complexes
Authors:Natarajan Thilagavathi  Chinnasamy Jayabalakrishnan
Institution:1.Department of Chemistry,Surya Engineering College,Tamil Nadu,India;2.Post Graduate and Research Department of Chemistry,Sri Ramakrishna Mission Vidyalaya College of Arts and Science,Coimbatore,India
Abstract:Ru(III) complexes of the type RuXB(L)2] have been prepared by the reaction of 3,4-dihydropyrimidin-2(1H)-ones/thiones (HL1–HL4) with the precursors of the type RuX3B3] where X=Cl or Br; B=PPh3 or AsPh3 and L is the deprotonated ligand. The synthesized complexes were characterized by physico-chemical methods, electrochemical and magnetic moment data. The catalytic efficiency of the complexes were examined in the oxidation of alcohols and antimicrobial studies were also carried out. MediaObjects/11532_2010_45_Fig1_HTML.jpg
Keywords:
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