Synthesis,characterization, catalytic and antimicrobial studies of ruthenium(III) complexes |
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Authors: | Natarajan Thilagavathi Chinnasamy Jayabalakrishnan |
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Institution: | 1.Department of Chemistry,Surya Engineering College,Tamil Nadu,India;2.Post Graduate and Research Department of Chemistry,Sri Ramakrishna Mission Vidyalaya College of Arts and Science,Coimbatore,India |
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Abstract: | Ru(III) complexes of the type RuXB(L)2] have been prepared by the reaction of 3,4-dihydropyrimidin-2(1H)-ones/thiones (HL1–HL4) with the precursors of the type RuX3B3] where X=Cl or Br; B=PPh3 or AsPh3 and L is the deprotonated ligand. The synthesized complexes were characterized by physico-chemical methods, electrochemical
and magnetic moment data. The catalytic efficiency of the complexes were examined in the oxidation of alcohols and antimicrobial
studies were also carried out.
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