| Synthesis and Crystal Structure of 9-[3-Oxo-1-（4-bromopheny）-3-phenypropyl] fluorine |
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| 作者姓名： | FENG Fu |
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| 作者单位： | School of Chemistry and Environmental Engineering, Hubei Institute for Nationalities, Enshi 445000, China |
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| 基金项目： | Supported by the Team Research for Excellent Mid-aged and Young Teachers of Higher Education of Hubei Province （T200707） |
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| 摘 要： | A novel compound of 9-3-oxo-1-(4-bromopheny)-3-phenypropyl]fluorine (3) was synthesized via nucleophilic addition reaction under solvent-free condition. Its structure was determined by IR, 1H NMR, MS, elemental analysis and X-ray diffraction. The crystal of the new compound is of triclinic system, space group P-1 with a=9.7919(16), b=11.0932(18), c=11.2534(19) , α=76.927(3), β=67.452(3), γ=84.895(3)°, V=1099.7(3) 3, Z=2, Dc=1.369 g/cm3, μ=1.886 mm-1, F(000)=464, R=0.0586 and wR=0.1562 for 3145 observed reflections with Ⅰ 2σ(Ⅰ). π-π Stacking interactions contribute to the stability of the structure.
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| 关 键 词： | 晶体结构 氧代 合成 亲核加成反应 氟 新化合物 无溶剂条件 X射线衍射 |
Synthesis and Crystal Structure of 9-[3-Oxo-1-(4-bromopheny)-3-phenypropyl]fluorine |
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| FENG Fu.Synthesis and Crystal Structure of 9-[3-Oxo-1-(4-bromopheny)-3-phenypropyl]fluorine[J].Chinese Journal of Structural Chemistry,2010,29(12):1760-1763. |
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| Authors: | FENG Fu |
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| Institution: | FENG Fu (School of Chemistry and Environmental Engineering, Hubei Institute for Nationalities, Enshi 445000, China) |
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| Abstract: | A novel compound of 9-3-oxo-1-(4-bromopheny)-3-phenypropyl]fluorine (3) was synthesized via nucleophilic addition reaction under solvent-free condition.Its structure was determined by IR,1H NMR,MS,elemental analysis and X-ray diffraction.The crystal of the new compound is of triclinic system,space group P1 with a=9.7919(16),b=11.0932(18),c=11.2534(19) A,α=76.927(3),β=67.452(3),γ=84.895(3)°,v=1099.7(3) A3,Z=2,Dc=1.369 g/cm3,μ=1.886 mm-1,F(000)=464,R=0.0586 and wR=0.1562 for 3145 observed reflections with I>2σ(I).π-π Stacking interactions contribute to the stability of the structure. |
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| Keywords: | fluorine chalcone Michael addition solvent-free crystal structure |
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