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The Characteristics of Mechanically Activated Mixtures of Copper Hydroxocarbonate With Aluminium
Authors:Wieczorek-Ciurowa  K  Shirokov  Ju G  Pary?o  M  Gamrat  K
Institution:(1) Institute of Inorganic Chemistry and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Cracow, Poland;(2) Ivanovo State Academy of Chemistry and Technology, Engels Prospect 7, 153-260 Ivanovo, Russia
Abstract:The chemical and physical processes occurring during grinding of copper hydroxocarbonates mixtures with aluminium were studied. A planetary ball mill was used. A thermogravimetry and X-ray powder diffraction method allowed to determine the composition of solid products after mechanical activation. The amount of the Cu2(OH)2CO3 undecomposed andAl2O3⋅3H2O, CuO, Al2O3, Cu0, CuxAly alloys and remained Al0 in the systems is strongly dependent on the duration of grinding and on the proportion of components. The comparative results are presented. This revised version was published online in July 2006 with corrections to the Cover Date.
Keywords:aluminium  catalysts  CuAl-alloys  grinding  malachite  mechanical activation  phase analysis  thermogravimetry  transition metals
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