Vinylidene complexes of transition metals : IV. The transfer of the phenylvinylidene ligand from manganese to rhenium. the novel binuclear complex Cp2MnRe(μ-CCHPh)(CO)4期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Vinylidene complexes of transition metals : IV. The transfer of the phenylvinylidene ligand from manganese to rhenium. the novel binuclear complex Cp2MnRe(μ-CCHPh)(CO)4

Authors:	N.E. Kolobova A.B. Antonova O.M. Khitrova

Affiliation:	Institute of Organo-Element Compounds, Academy of Sciences of the U.S.S.R., Vavilov Str. 28, Moscow B-312 U.S.S.R.

Abstract:	The novel complex Cp₂MnRe(μ-CCHPh)(CO)₄ (I) containing the bridging phenylvinylidene ligand and MnRe bond was obtained in the reaction of CpMn(CCHPh)(CO)₂ with CpRe(CO)₂·THF. Complex I turns into CpRe(CCHPh)(CO)₂ under normal conditions. This is the first example of the transfer of the vinylidene ligand from one transition metal to another.

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