Gas phase nucleophilic substitution reactions; Transaminations of silanamines |
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| Authors: | Kenneth J Shea Robert Gobeille James F Wolf |
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| Institution: | Department of Chemistry, University of California, Irvine, CA 92717 U.S.A. |
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| Abstract: | Ion cyclotron resonance spectroscopy has been employed in the study of gas phase transaminations of silanamines. The dominant reaction pathway is found to involve a bimolecular nucleophilic substitution at silicon. Under suitable conditions the ICR method permits direct observation of intermediate reaction complexes. The possible relationship of these complexes to SN2 intermediates is discussed. |
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