Cyanomethyl cyclopentadienyl complexes of cobalt |
| |
| Authors: | P Royo J Sancho |
| |
| Institution: | Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Murcia Spain |
| |
| Abstract: | The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type CpCo(CH2CN)(bipy)]+ BPh4? and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
