The crystal and molecular structure of the dimethylplatinum(II) complex of 1,1,1-tris(diphenylphosphinomethyl)ethane |
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| Authors: | Richard M. Kirchner Robert G. Little Kwoliang D. Tau Devon W. Meek |
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| Affiliation: | Department of Chemistry, Manhattan College, Riverdale, New York 10471 U.S.A.;Department of Chemistry, University of Maryland, Baltimore County, Catonsville, Maryland 21228 U.S.A.;Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 U.S.A. |
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| Abstract: | A new crystal X-ray study, as well as proton and phosphorus-31 NMR studies, show that the structure of Pt(CH3)2(tripod) [tripod = 1,1,1-tris(diphenylphosphinomethyl)ethane] consists of a four-coordinate, nearly planar platinum with the triphosphine functioning as a bidentate ligand. |
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| Keywords: | Address correspondence to this author at: Sterling Chemistry Laboratroy Yale University 225 Prospect St. New Haven Ct. 06520 (U.S.A.) |
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