A tri-coordinate hydrogen ligand in a trinuclear iridium cluster |
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| Authors: | Daniel F. Chodosh Robert H. Crabtree Hugh Felkin George E. Morris |
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| Affiliation: | Sterling Chemistry Laboratory. Yale University, 225 Prospect St., New Haven, Conn. 06520 U.S.A.;Institut de Chimie des Substances Naturelles, C.N.R.S., 91190, Gif-sur-Yvette France |
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| Abstract: | The novel complex [{IrH2,(PCy3)(C5H5N)}3(μ3-H)] [PF6]2 has been characterized by X-ray crystallography, IR and 1H NMR spectroscopy. It contains a tricoordinate hydrogen ligand within a triangle of iridium atoms. |
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