η5:η5-Bicyclopentadienylmolybdenum chemistry: Some alkyl,halo and thiol derivatives |
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| Authors: | Malcolm LH Green Stephen J Simpson |
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| Institution: | Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QRGreat Britain |
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| Abstract: | The preparation of the compounds {(η-C5H5)MoX}2{μ-(η5-C5H4-η5-C5H4)} (X = Me, PhCH2, Me3SiCH2, Br) and {(η-C5H5)MoY2}2{μ-(η5-C5H4-η5-C5H4)}, (Y = H, I, SMe, S-n-Bu) is described. Photolysis of {(η-C5H5)MoH}2 {μ-(η1:η5 -C5H4)}2 and {(η-C5H5)MoH}2{(η5-C5H4-η5-C5H4)} in benzene leads to a compound of stoichiometry C20H18Mo2. |
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